一般来说固体碱KOH或者NaOH只要密闭保存不受潮,就可以使用,不存在保质期的问题。液体的KOH或者NaOH也是只要不因为水分蒸发而变成碳酸类物质;没有杂质进入和碱液反应,也是可以一直使用,没有保质期的问题。
Generally speaking, solid alkali KOH or NaOH can be used as long as it is sealed and stored without moisture, without any shelf life issues. The KOH or NaOH of liquid is also as long as it does not become carbonated substances due to water evaporation; No impurities enter and react with alkaline solution, and it can be used continuously without any shelf life issues.
NaOH密闭保存,有的3、5年都没事。但是,固体KOH貌似要比固体NaOH就更容易受潮。有人反馈说,前几天才发现:九个月前买的密封着的固体KOH,竟然受潮了。而且还把密封的塑料瓶给“烧”坏了。被“烧”坏的塑料瓶惨不忍睹。
NaOH is kept tightly sealed, and some will be fine for 3 to 5 years. However, solid KOH appears to be more susceptible to moisture than solid NaOH. Some people have reported that they discovered a few days ago that the sealed solid KOH they bought nine months ago was actually damp. And also burned the sealed plastic bottle. The plastic bottle that was burned out is unbearable.
装固体KOH的塑料瓶的纸壳箱的一角留下了:受潮后生成的K2CO3与水的混合物。
A corner of the cardboard box containing solid KOH plastic bottles is left: a mixture of K2CO3 and water generated after being damp.
CO2+2KOH═K2CO3+H2O
CO2+2KOH═K2CO3+H2O
更神奇的是:K2CO3与水的混合物还击穿了第一个纸壳箱,直接渗透到了第二个纸壳箱里,在第二个纸壳箱里留下了大量的水溶液。堪称大型车祸现场。足以看出KOH一旦受潮有多可怕了!
What's even more magical is that the mixture of K2CO3 and water also penetrated the first cardboard box and directly penetrated into the second cardboard box, leaving a large amount of aqueous solution in the second cardboard box. It can be considered a scene of a major car accident. It's enough to see how terrifying KOH can be once it gets damp!
氢氧化钾固体可装入0.5毫米厚的钢桶中严封,每桶净重不超过100公斤;塑料袋或二层牛皮纸袋外全开口或中开口钢桶;螺纹口玻璃瓶、铁盖压口玻璃瓶、塑料瓶或金属桶(罐)外普通木箱;螺纹口玻璃瓶、塑料瓶或镀锡薄钢板桶(罐)外满底板花格箱、纤维板箱或胶合板箱;镀锡薄钢板桶(罐)、金属桶(罐)、塑料瓶或金属软管外瓦楞纸箱。
Potassium hydroxide solid can be tightly sealed in 0.5mm thick steel drums, with a net weight of no more than 100 kilograms per drum; Plastic bags or two-layer kraft paper bags with full or medium opening steel drums; Thread mouth glass bottles, iron cap pressure mouth glass bottles, plastic bottles or ordinary wooden boxes outside metal barrels (cans); A threaded glass bottle, plastic bottle, or tinned thin steel plate barrel (can) with a bottom plate full of checkered boxes, fiberboard boxes, or plywood boxes; Tinned thin steel drums (cans), metal drums (cans), plastic bottles or corrugated cardboard boxes with metal hoses.
铁路运输时,钢桶包装的可用敞车运输。起运时包装要完整,装载应稳妥。运输过程中要确保容器不泄漏、不倒塌、不坠落、不损坏。严禁与易燃物或可燃物、酸类、食用化学品等混装混运。运输时运输车辆应配备泄漏应急处理设备;
During railway transportation, steel drum packaging can be transported by gondola cars. The packaging should be complete during shipment and the loading should be secure. During transportation, it is necessary to ensure that the container does not leak, collapse, fall, or be damaged. It is strictly prohibited to mix and transport flammable or combustible materials, acids, edible chemicals, etc. Transport vehicles should be equipped with leakage emergency response equipment during transportation;
Store in a cool, dry, and well ventilated warehouse. Keep away from sparks and heat sources. The humidity Z in the warehouse should not exceed 85%. The packaging must be sealed and protected from moisture. It should be stored separately from flammable (combustible) substances, acids, etc., and mixed storage should be avoided. The storage area should be equipped with suitable materials to contain leaks. For more related matters, come to our website http://qxu1539600089.my3w.com Consult and understand!